Monday, December 22, 2008

ACID RAIN

Acid deposition is a general term that includes more than simply acid rain. Acid deposition primarily results from the transformation of sulphur dioxide (SO2) and nitrogen oxides into dry or moist secondary pollutants such as sulphuric acid (H2SO4), ammonium nitrate (NH4NO3) and nitric acid (HNO3). The transformation of SO2 and NOx to acidic particles and vapours occurs as these pollutants are transported in the atmosphere over distances of hundreds to thousands of kilometers. Acidic particles and vapours are deposited via two processes - wet and dry deposition. Wet deposition is acid rain, the process by which acids with a pH normally below 5.6 are removed from the atmosphere in rain, snow, sleet or hail. Dry deposition takes place when particles such as fly ash, sulphates, nitrates, and gases (such as SO2 and NOx), are deposited on, or absorbed onto, surfaces. The gases can then be converted into acids when they contact water
An acid is a substance with a sour taste that is characterized chemically by the ability to react with a base to form a salt. Acids turn blue litmus paper (also called pH paper) red. Strong acids can burn your skin A pH scale is used to measure the amount of acid in a liquid-like water. Because acids release hydrogen ions, the acid content of a solution is based on the concentration of hydrogen ions and is expressed as "pH." This scale is used to measure the acidity of rain samples.
The smaller the number on the pH scale, the more acidic the substance is. Rain measuring between 0 and 5 on the pH scale is acidic and therefore called "acid rain." Small number changes on the pH scale actually mean large changes in acidity.For example, a change in just one unit from pH 6.0 to pH 5.0 would indicate a tenfold increase in acidity. Clean rain usually has a pH of 5.6. It is slightly acidic because of carbon dioxide which is naturally present in the atmosphere. Vinegar, by comparison, is very acidic and has a pH of 3.
Sulphur dioxide (SO2) is generally a byproduct of industrial processes and burning of fossil fuels. Ore smelting, coal-fired power generators and natural gas processing are the main contributors. In 2000, for instance, U.S. SO2 emissions were measured at 14.8 million tonnes - more than six times greater than Canada's 2.4 million tonnes. But the sources of SO2 emissions from the two countries are different. In Canada, 68% of emissions come from industrial sources and 27% comes from electric utilities (2000). In the U.S., 67% of emissions are from electric utilities (2002).

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